交聯(lián)染色用非醛交聯(lián)劑的合成與應(yīng)用

1、大連理工大學(xué)碩士學(xué)位論文交聯(lián)染色用非醛交聯(lián)劑的合成與應(yīng)用姓名：侯文杰申請(qǐng)學(xué)位級(jí)別：碩士專(zhuān)業(yè)：應(yīng)用化學(xué)指導(dǎo)教師：張淑芬楊錦宗20020601交聯(lián)染邑用非醚蹙聯(lián)劑的臺(tái)成0應(yīng)用ABSTRACTTheclearadvantageofcrosslinkingdyescontainingnucleophilicgroupshasformingconvalentbondsbetweendyesandfabricsbycrosslinking。Andc

2、rosslinkingdyescontainedmanynucleophilicgroups，itmightbeexpectedthat100％fixationofdyescouldbeobtainedwithgoodfastnesspropertiesInthispapercrosslinkingagentandcrosslinkingagent2werepreparedusingCyanuricchlorideand4Aminoph

3、enyl一一snlphatoethylsul馥oneasrawmaterialsandindentifiedbyFT—TRspectraandMSBesides，crosslinkingagent3wasalsopreparedandindentifiedbyFT—TRspectraandMSThepolyaminedyewasappliedonsilkandcottonviadippingandpaddingdyeingprocess

4、。Thedyedfabricswerefixedbycrosslinkingagentl，2，3andmodified2Dusingdip—pad—cureanddippad—steamfixationmethodsTheeffectsofcrosslinkingagentconcentrationandpHvaluesondyefixationwerestudiedTheresultsshowedthattheeffectsusing

5、crosslinkingagentl，2and3werebetterthanmodified2D。強(qiáng)efixationvaluesofthebluepolyaminedyeonfabricswerealiabove99％usingerosslinkingagent12and3Washthewetfastnessofthebluepolyaminedyewereabove45Themostfixationvalueoftheorangep

6、olyaminedyeonfabricswas959％Thewetfastnessoftheorangepolyamineayewereabove4—5。ThepolyvinylaminedyeWasappliedonsilkandcottonviapaddingdyeingprocessThedyedfabricswerefixedbycrosslinkingagent13usingdip—pad—curefixationmethod

7、“[qaeeffectsofcrosslinkingagentconcentrationandpHvaluesondyefixationwerestudiedTheresultsshowedthalthefixationvaluesofthebluepolyvinylaminedyeonfabricswereallabove99％usingcrosslinkingagentL3Thewetfastnessofthebluepolyami

8、nedyewereabove4—5，Thepolyallylaminedyewasappliedonsilkviadippingdyeingprocess。Thedyedfabricswerefixedbycrosslinkingagentlusingdippad—curefixationmethod，TheeffectsofcrosslinkingagentconcentrationandpHvaluesondyefixationwe

9、restudiedTheresultsshowedthatthefixationvaluesofthebluepolyallylaminedyeonfabricswereallabove99％usingcrosslinkingagentl，3Thewetfastnessofthebluepolyaminedyewereabove4—5Keywords：crosslinkingdyes，erosslinkingagenterosslink