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1、Introduction很多文獻已很多文獻已經(jīng)討論過經(jīng)討論過了A.Solarenergyconversionbyphotoelectrochemicalcellshasbeenintensivelyinvestigated.(Nature1991353737740)B.Thiswasdemonstratedinanumberofstudiesthatshowedthatcompositeplasmonicmetalsemiconduct
2、photocatalystsachievedsignificantlyhigherratesinvariousphotocatalyticreactionscomparedwiththeirpuresemiconductcounterparts.C.SeveralexcellentreviewsdescribingtheseapplicationsareavailablewedonotdiscussthesetopicsD.Muchwk
3、sofarhasfocusedonwidebgapsemiconductsfwatersplittingfthesakeofchemicalstability.(DOI:10.1038NMAT3151)E.RecentdevelopmentsofLewisacidswatersolubleganometalliccatalystshaveattractedmuchattention.(Chem.Rev.20021023641?3666)
4、F.AninterestingapproachintheuseofzeoliteasawatertolerantsolidacidwasdescribedbyOgawaetal(Chem.Rev.20021023641?3666)G.Considerableresearchefftshavebeendevotedtothedirecttransitionmetalcatalyzedconversionofarylhalidestoary
5、lnitriles.(J.g.Chem.20006579847989)H.TherearemanyexcellentreviewsintheliteraturedealingwiththebasicconceptsofthephotocatalyticprocessthereaderisreferredinparticulartothosebyHoffmanncowkersMillscowkersKamat.(Metaloxidecat
6、alysis19P755)I.NishimiyaTsutsumihavereptedon(proposed)theinfluenceoftheSiAlratioofvariouszeolitesontheacidstrengthwhichwereestimatedbycalimetryusingammonia.(Chem.Rev.20021023641?3666)二、在resultsdiscussion中經(jīng)常會用到的:如圖所示所示B.A
7、notherinterestingfindingisthatzeoliteswith10memberedringpesshowedhighivities(99%)tocyclohexanolwhereasthosewith12memberedringpessuchasmdeniteproducedlargeamountsofdicyclohexylether.(Chem.Rev.20021023641?3666)C.Itshouldbe
8、pointedoutthatthenanometerscaledistributionofelectrocatalystcentersontheelectrodesurfaceisalsoapredominantfactfhighRelectrocatalyticactivity.D.NotablytheRuIIRhIcomplexespossessingthesameBINAPchiralityfmantipodalaminoacid
9、sasthepredominantproducts.(Angew.Chem.Int.Ed.200241:2008–2022)E.Giventhemultitudeofvarioustransfmationspublisheditisnotewthythatonlyveryfewdistinctactivationmethodshavebeenidentified.(Chem.Soc.Rev.20093821782189)F.Itisim
10、ptanttohighlightthatthesetwodirectingeffectswillleadtodifferentenantiomersoftheproductsevenifboththe“Hbondcatalyst”thecatalystactingbystericshieldinghavethesameabsolutestereochemistry.(Chem.Soc.Rev.20093821782189)G.Itisw
11、thwhilementioningthatthesePPNDscanbeverystablefseveralmonthswithouttheobservationsofanyfloatingprecipitateddotswhichisattributedtotheelectrostaticrepulsionsbetweenthepositivelygePPNDsresultinginelectrostericstabilization
12、.(Adv.Mater.201224:2037–2041)2....仍然是個挑戰(zhàn)A.ThereistherebyanurgentneedbutitisstillasignificantchallengetorationallydesigndelicatelytailtheelectroactiveMTMOsfadvancedLIBsECsMOBsFCs.(Angew.Chem.Int.Ed.2014531488–1504)B.Howev
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