Ⅰ全氟磺酰氟樹(shù)脂負(fù)載的鈀催化劑的合成與應(yīng)用Ⅱ己二酸的綠色合成.pdf

1、復(fù)旦大學(xué)碩士學(xué)位論文Ⅰ全氟磺酰氟樹(shù)脂負(fù)載的鈀催化劑的合成與應(yīng)用Ⅱ己二酸的綠色合成姓名：連慧申請(qǐng)學(xué)位級(jí)別：碩士專業(yè)：有機(jī)化學(xué)指導(dǎo)教師：丁宗彪20030520復(fù)旦大學(xué)碩士學(xué)位論文Abs訂actAbstractWiththerapiddevelopmentof“green’’chemistryscientistshopethatinorganicoxidations，watercatlreplaceorganicsolvents，and“gr

2、eenoxidants”suchasairoxygenorhydrogenperoxideCanreplacetraditionaloxidantsthatcarlgeneratecopiOUSamountsofwasteandpollutionMucha囂entionhasbeendrawntocatatyticoxidations，oneofthemostimportantreactionforfimctionalgrouptran

3、sformationinorganicsynthesisNowadays，theresearchemphasishasrecentlyswitchedtothesearchfornovelcatalystswithhighactivityhighstabilityandeasyrecoveryInthisthesiswemainlydiscusstwokindsofworkthatisassociated晰m“green”chemist

4、ryOneisthesynthesisandapplicationofperfluorinatedpolymer—supportedPd(II)catalysts，theotheristhesynthesisofadipicacidwitha“green”routePolymersupportedcatalystsareadvantageousoverthetraditionalonesinmanyaspects，suchaseasys

5、eparationfromthereactionmixtureandrecyclingTheapplicationofPolymersupportedcatalystsisaclearexampleof“green”chemistryinwhichthewastestreamsanddepletionofresourcesassociatedwithtransitionmetalsisminimized，Inthefirstpartof

6、thethesis，thepeffluorinatedpolymersupportedPd(II)catalystswereprepared，andtheirapplicationintheoxidationsofalcoholshasbeeninvestigatedWiththeassistanceofmicrowave，5amino一1，10phenanthrolineandalso4aminopyridinewerecovalen

7、tlylinkedtotheperfluorinatedpolymerNationTwoPd(II)catalysts(8，卵wereobtainedbycoordinationeffectsofPd(II)saltswiththeattachedligandsThecatalyticactivitywereassessedusingtheoxidationreactionofalcoholstocarbonylcompoundsOur

8、resultsexhibitedthataromaticalcoholscaIlbeoxidizedtothecorrespondingketonesoraldehydesefficientlyusingthenovelPd(II)catalystswhilstaliphaticalcoholsbehavedpoorlyItWasfoundthatbothofthecatalystSarereusableatleast5timesOth

9、erwise，tentativelywesynthesizedcatalyst10whichwastheproductofcoordinationeffectsofPd(II)saltsandpolystyrene—bound4aminopyridineAdipicacidisnecessaryforthemanufactureoffibres，andtheindustrialprocessesofitsproductionCangen