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1、Definition材料的定義材料的定義:Thematerialsmakingupthesurroundingwldconsistofdiscreteparticleshavingasubmicroscopicsize.Atomicstructurethenatureofbonds(原子原子結(jié)構(gòu)和化學(xué)鍵結(jié)構(gòu)和化學(xué)鍵)—metalstheiralloys(metallicbonding金屬鍵)—ganicpolymers有機(jī)聚合物(cov
2、alentbondingsecondarybonding共價鍵和二次鍵)—ceramics(ionicbondingcovalentbonding)Mechanicalproperties:力學(xué)性能:力學(xué)性能Whichreflectthebehaviofmaterialsdefmedbyasetoffces(概念)Fourbasictypesofstresses:tensilecompressivesheartsion(拉力,壓力,剪切
3、力,扭轉(zhuǎn)力)Physicalproperties:物理性能物理性能thebehaviofmaterialssubjectedtotheactionoftemperatureelectricmagicfieldslight.電性能Electricproperties磁性能Magicproperties熱性能Thermalproperties光性能OpticalpropertiesChemicalproperties:化學(xué)性能化學(xué)性能Whi
4、chacterizethebehaviofmaterialinareactiveenvironment.(概念)Thefourbasicaspectsofmaterialssciencetechnologyare:manufacturingprocessingstructurepropertiesperfmances結(jié)構(gòu)-性能-工藝之間的關(guān)系:結(jié)構(gòu)-性能-工藝之間的關(guān)系:Firsttheprocessingofamaterialaffe
5、ctsthestructuresecondtheiginalstructurepropertiesdeterminehowwecanprocessthematerialtoproduceadesiredshape一、METAL:(金屬金屬)1、金屬最顯著的特性:goodconductsofheatelectricity(熱導(dǎo)性,電導(dǎo)性)2、性能性能:areopaquetovisiblelightarehardrigidcanunderg
6、oplasticdefmationhaveahighmeltingtemperature3、金屬的晶體點(diǎn)陣:crystalstructure(晶體結(jié)構(gòu)):bodycenteredcubicstructurefacecenteredcubicstructurehexagonalclosepackedstructure(體型、面型,六角形放射狀)4、propertiesofalloys(合金的性能):(mecarbonmebrittle.)
7、haverelativelyhighthermalelectricalconductivitiesgoodenergyabsptionacteristicsnonmagicproperties5、鑄鐵概念:鑄鐵概念:castironessentiallyanalloyofironcarbonsiliconiscomposedofironfrom2to6.67percentcarbonplusmanganesesulfurphosphus
8、shapedbybeingcastinamold.6、Thetypespropertiesofcastiron;whitecastiron(hardbrittle)graycastiron(brittlewithstlargecompressiveloadsbutsmalltensileloads)alloycastironnodularductilecastiron(goodcastabilitytoughnessgoodwearre
9、sistancelowmeltingpointhardenability)malleablecastiron(strengthtoughnessductilitymachinability)7、carbonsteels(碳鋼):lowcarbonsteels(含碳0.05~0.32%);mediumcarbonsteels(含碳0.35~0.55%);highcarbonsteels(含碳0.60~1.50%)8、不銹鋼不銹鋼:ther
10、earethreetypesofstainlesssteels:themartensitictypes;theferritictypes;theaustenitictypes9、advantagesofusingAl:onethirdoftheweightofsteelgoodthermalelectricalconductivityhighstrengthtoweightratiocanbegivenahardsurfacebyano
11、dizinghardcoatingmostalloysareweldablewillnotrusthighreflectivitycanbediecasteasilymachinedgoodfmabilitynonmagicnontoxicone–thirdofthestiffnessofsteel.10、copperisknownfitshighthermal(熱導(dǎo)熱導(dǎo)性)electricalconductivity.11、cryst
12、alstructure:bodycenteredcubicstructure(barium)facecenteredcubicstructure(copper)hexagonalclosepackedstructure(zinc)二、CERAMIC(陶瓷陶瓷)1、Thepropertyofceramics(陶瓷的性質(zhì)陶瓷的性質(zhì))?Extremehardness(硬度高硬度高)?Heatresistance?Crosionresistan
13、ce?Lowelectricalthermalconductivity?Lowductility(brittleness)2、Posity(孔隙度孔隙度)Openposity:referstothewkofpesinamaterialthatisopentothesurfaceintowhichaliquidsuchaswatercanperateifthepartweresubmergedinit。Closedposity:refer
14、stothosepesthathavebecomesealedwithinthegrainstructure。initiation(birth)鏈引發(fā)propagation(growth)鏈增長termination(death)鏈終止TerminationReaction:Terminationtypicallyoccursintwoways:combination(偶合終止偶合終止)disproptionate(歧化終止歧化終止)C
15、ombinationoccurswhenthepolymer’sgrowthisstoppedbyfreeelectronsfromtwogrowingchainsthatjoinfmasinglechain.反應(yīng)式Disproptionationhaltsthepropagationreactionwhenafreeradicalstripsahydrogenatomfromanactivechain.Acarboncarbondou
16、blebondtakestheplaceofthemissinghydrogen.反應(yīng)式Livingpolymerization:Thereexistsatypeofadditionpolymerizationthatdoesnotundergoaterminationreaction.Thissocalled“l(fā)ivingpolymerization”continuesuntilthemonomersupplyhasbeenexhau
17、stedPolymersvaryintheirmechanicalbehavidependingonthedegreeofcrystallinitydegreeofcrosslinkingthevaluesofTgTm.Therearetwotypesofplastics:—flexibleplastics(柔性塑料)(柔性塑料)rigidplastics(剛性塑(剛性塑料)料).Theflexibleplasticspossessmo
18、deratetohighdegreesofcrystallinityawiderangeofTmTgvalues.Theyhavemoderatetohightensilestrengthsultimateelongation.Therigidplasticshavehighmodulimoderatetohightensilestrengthstheyundergoverysmallelongationsbeferupturing.T
19、mpoltofmelttemperatureTgglasstransitiontemperatureTgTm=0.50.8AhighlyflexiblechainhasalowTgstrongintermolecularfcestendtoraiseTgalsoincreasecrystallinitythecontrollingfactindeterminingTgischainflexibility六、COMPOSITE(復(fù)合材料)
20、(復(fù)合材料)DefinitionofComposite(復(fù)合材料的定義復(fù)合材料的定義)?Acompositeisacombinedmaterialcreatedbythesyntheticassemblyoftwomecomponentsaedfillerreinfcingagentacompatiblematrix(基體)binder(e.g.aresin)indertoobtainspecificacteristicspropert
21、ies.AdvantagesofusingComposites:Compositesaresuperitometalsfmanyapplicationsdueto(優(yōu)點(diǎn))(優(yōu)點(diǎn))?Highstrengths?Stiffnesses?Easeofmouldingcomplexshapes?Highenvironmentalresistance?LowdensitiesThepropertiesofthecompositearedeterm
22、inedby:?Thepropertiesofthefibre?Thepropertiesoftheresin?Theratiooffibertoresininthecomposite(FiberVolumeFraction(FVF))?ThegeometryientationofthefibresinthecompositeMatrixcomposite(基復(fù)合材料基復(fù)合材料)PolymerMatrixCompositesMetalM
23、atrixCompositesCeramicMatrixComposites.(樹脂基復(fù)合材料、金屬基復(fù)樹脂基復(fù)合材料、金屬基復(fù)合材料、陶瓷基復(fù)合材料。合材料、陶瓷基復(fù)合材料。)Physicalproperties:(物理性質(zhì)物理性質(zhì))whichdescribethebehaviofmaterialssubjectedtotheactionoftemperatureelectricmagicfieldslightChemicalprop
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