小分子與過渡金屬Ag（Ⅰ），Cu（Ⅱ），Ni（Ⅱ），Co（Ⅱ）配合物的合成，結(jié)構(gòu)和生物活性的研究.pdf

1、蘭州大學碩士學位論文小分子與過渡金屬Ag（Ⅰ），Cu（Ⅱ），Ni（Ⅱ），Co（Ⅱ）配合物的合成，結(jié)構(gòu)和生物活性的研究姓名：劉昭第申請學位級別：碩士專業(yè)：無機化學指導教師：譚民裕朱海亮20050501AbstractWhereasthedevelopmentofreliablemethodsforthepredictionofcrystalstructureandtherationalsynthesisoffunctionalcoordi

2、nationcomplexesremainsallelusivescientificchallenge，itsrelevancetoaspectsofpharmaceuticalandmaterialssciencehasfueledrapiddevelopmentoftheconceptofcrystalengineeringTheaimofthisworkistoinvestigatehowtocontrolthestructure

3、sofsometrasitionmetalswithsimplemolecularsfunctionalcoordinationandthemoleculararchitecturesAbriefdescriptioniSbelow：(1)FourpolymercomplexesontheA烈I)一simplemolecularandonedinuclearcomplexesweresynthesizedinthedissertatio

4、n：Na[Ag(NH2SOa)2]n(1)(C6H14N2)【Ag(NcsMn(2)[A92(C2HsN2)3][A92(CsHioN203)2]’2H20)。(3)CAg(C6HIsN4)】(Ci04))n(4)[AgffCl4H804)(CsH6N2)2】(5)(2)Three12，44dzolecomplexesweresynthesized[Cu(C104)2(C19HlsN5)2](6)[Ni(C19HIsNs)2(H20)2