三種二茂鐵芐基叔胺的合成及其環(huán)金屬化（Hg、Pd）反應(yīng).pdf

1、天津大學(xué)碩士學(xué)位論文三種二茂鐵芐基叔胺的合成及其環(huán)金屬化（Hg、Pd）反應(yīng)姓名：耿鳳英申請(qǐng)學(xué)位級(jí)別：碩士專業(yè)：有機(jī)化學(xué)指導(dǎo)教師：王洪星20070101ABSTRACT’Condensanonofacetylferroceneandseriessubstitutedbenzylannnesinetheratroomtemperatureresulmdinferrocenylaldimines[(礦一CsHs)Fe[rtCsH4C(CH3)

2、=NCH2C6H4R)]，R=4MeO(a)，4一Me(b)，H(c)inmoderateyieldsReductionoftheseimineswithsodiumborohydrideinmethanolorlithiumaluminumhydrideinTHFproducedquantitativesecondaryferrocenylamines[(礦CsHs)Fe[礦一CsH4CH(CH3)NHCH2C6H4R)]，R=4一M

3、eO(a)，4Me(b)，H(c)Reductivemethylationofsecondaryferrocenylaminesasmentionedabove麗thsodiumcyanoborohydride，formaldehydeinaceticacidgaveoutthecorrespondingtertiaryferrocenylamines【(礦一CsHs)Fef礦CsH4CH(CH3)N(CH3)CH2C6H4R)]，R=

4、4MeO(a)，4—Me(b)，H(c)OrthomercurationofthesetertiaryaminesaffordedorthomercuratedcomplexesinwhichanintramolecularN—HgcoordinationpatternwasobservedCyclopalladationoftheseaminesledtoracemiccyclopalladatedcomplexesinlowyiel

5、dsThestereoselectiveCHactivationwasobservedThestructuresthecompoundsasmentionedbeforewerecharacterizedbyelementalanalysis，IRand1HNMRInaddition，thestructuresofthreecyclopalladatedcomplexesandonemercuratedcomplexwerealsoco