γ-內(nèi)酯的酶法動力學(xué)拆分以及α-支鏈醛的不對稱氫轉(zhuǎn)移動態(tài)動力學(xué)拆分.pdf

1、蘇州大學(xué)碩士學(xué)位論文γ內(nèi)酯的酶法動力學(xué)拆分以及α支鏈醛的不對稱氫轉(zhuǎn)移動態(tài)動力學(xué)拆分姓名：吳國峰申請學(xué)位級別：碩士專業(yè)：有機(jī)化學(xué)指導(dǎo)教師：張雅文20080501英文摘要EnzymaticResolutionof嚴(yán)LactonesandDynamicKineticResolutionof弘BranchedAldehydesbyUsingAsymmetricTransferHydrogenationReactionABSTRACT1Prepa

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5、genationofaseriesof2一alkyl肛ketoaldehydes1a一1pusingHC00H：Et3N=5：2asmehydrogenso眥eand㈣一TsDPENbaLsedRu(II)catalysts1，砌dyn疵c虹neticresolutionproccedstosyn_t11esizecorresponding2猷kyl盧ket0p血1啊alcohols2a2pwithgoodyields鋤dmoderat

6、eeeValuesnlesereaCtionso毹ranaltemativefort：hepr印aIationofaldoltypeimemediatesbya110naldolpathway3DynamicKineticResolutionof西7rosylAldehydesbyUsingAsymmetricTtansferHydrogenationEnatioselectivereductionof仿tosylaldehydes10