含1，2，3-三氮唑杯[4]芳烴及水溶性杯芳烴的合成與性能研究.pdf

1、華中師范大學(xué)碩士學(xué)位論文含1，2，3三氮唑杯[4]芳烴及水溶性杯芳烴的合成與性能研究姓名：陳明亮申請(qǐng)學(xué)位級(jí)別：碩士專業(yè)：有機(jī)化學(xué)指導(dǎo)教師：李海兵20080401⑨碩士學(xué)位論文MASTER’STHESISAbstractCalixarenes，WIlicharebaSketsh印edmacrocycliccompoulldsofpotentialinterestforhost—gueStcomplexationstudies，repres

2、entthenewtypeofreceptoraRercyclodextriIlsaIldcrownethersDueto廿1eireasy劬ctionalizationaIldstl0ngcoHlplexiIlgpropertiestowardscations，aIlionsarldneu乜a1molecules，theyhavereceiVedparticularintereStsofmⅡnerouschemistsinrecent

3、yearsFunctionalcalixareneshaVebeenappliedsuccess如llyt0biomimeticresearch，separationsciencemldtecllllologyIntroducingheterocyclic行agmentsintomemoleculesisonee伍cient印proachtomodi匆t11estrIlctureofcalixarenesInthisdisse刪ion，

4、novelderivativesofcalix2Lrenescontailling1，2，3仃iazole、№resynmesizedtllrougllclickchemis臼yAttlles鋤etime，wate卜solublecalixarenesweresynthesizedarldtlleir印plicationassta_bleligaIldsofqu鋤加mdotswasstudiedThemaincontentsareaus

5、follow：1TherecentdeVelopmentofcalixarenesisimroducedAreviewoftlleirs仃Ilc眥s，syIltlleses，chemicalmodifications，propertiesandpotentialapplicationisoutlined，、ⅣitllpanicularemphaSisgiventowate卜solublecalixarenes2Utilizingclic

6、kchemis仃yl，2，3一仃iazolesubstitutedcalix[4】arenesderivativesweredesignedandsyntllesizedTheazidesubstitutedintemediates，whichhadbeenobtainedfrombromide，reactedconciselywim1，3一dipropyllyloxycalix【4】areneusingCu(I)catalysttop

7、reparetargetmolecules：3p—Sulfonatedcalix[4，6】areneandpsulf0natedtlliacalixarenewerepreparedaccordingt0liter砷L(zhǎng)lresandidentified4TbimproVeⅥ俄er。soluble￡Lbili夠ofquantumdots，weusedpsulfonatocalixarenewhichhavewatersolubleabil

8、ityaS廿lemnctionalmatIeri2Ll，preparingthewatersolublequaIlltumdotsThent11eopticalpropeniesofwatersolubleql鼬JIIldotsweresnldiedKeywords：calixarenes，wltersolublecalixarenes，1，3dipolarcycloaddition，clickchemist巧，quaIItllIlld