芳胺-鉬磷酸電荷轉(zhuǎn)移型雜化材料的合成、表征以及光色性研究.pdf

1、Y761560委伽犬孚碩士學(xué)位論文(2005屆)芳胺一鉬磷酸電荷轉(zhuǎn)移型雜化材料的合成、表征以及光色性研究Synthesis、characteristicandphotochromismofcharge。transferarylaminemolybdophosphorlcaicdhybridmaterials研究生姓名籃堡指導(dǎo)教師姓名固垂望塾攮專業(yè)名稱盟盤生研究方向塹型盟鯉撾趕論文提交日期2Q業(yè)主旦Synthesis、characteri

2、sticandphotochromismofchargetransferarylaminemolybdophosphoricaicdhybridmaterialsAbstractFourchargetransferhybridmaterialswerepreparedbYarylamineandKegginslaueturemolybdophosphoricacidinliquidphaseAndallhybridmaterialswe

3、recharacterizedThepropertyofphotochromismofhybridmaterialswerestudiedTheresultwereasfollows：1MakeconditionalexperimenttopreparehybridmaterialswithdiffeafentproportioninliquidphaseMakesorethemolecularformulaofhybndmateria

4、lsbyelementanalysis、ICPAESAASandTG；ThespectrumofIR、XRDandCVindicatetheKegginofheteropolyacidremainunchangedinthehybridmaterials2ThespectrumofESRandUVvisindicatechargetransferoccurbetweenaromaticamineandKegglnstructuremol

5、ybdophosphoncacidwhichleadtomeformationofmixedvalencecompound3PreparesinglecrystalwitlldiffusionmethodonlyacquirethesinglecrystalofDMAPM012，andanalysisthefinestructureofthesinglewystalTheresultindicatearomaticamineiscont

6、actedwimheteropolyacidbyhydrogenbondtoformtwodimensionalsupermolecule4ThephotochromismofhybridmaterialsweredifferentwhenhybridmaterialsWasindifferentstateStudythepropertyofphotochromismofhybndmaterialsinDMFsolutionandPVA

7、filmrespectivelyTheresultshowfourhybddmaterialshaveexcellentphotochromismbothinDMFsolutionandPVAfilmbutthephenomenonofphotochromismisdifferent，becausethemechanismisdifferentHaveinvertibilityinDMFsolution，canbeuseaserasab